Environmental Control of Triplet Emission in Donor–Bridge–Acceptor Organometallics

Carbene‐metal‐amides (CMAs) are a promising family of donor–bridge–acceptor molecular charge‐transfer (CT) emitters for organic light‐emitting diodes. A universal approach is demonstrated to tune the energy of their CT emission. A blueshift of up to 210 meV is achievable in solid state via dilution in a polar host matrix. The origin of this shift has two components: constraint of thermally‐activated triplet diffusion, and electrostatic interactions between guest and polar host. This allows the emission of mid‐green CMA archetypes to be tuned to sky blue without chemical modifications. Monte‐Carlo simulations based on a Marcus‐type transfer integral successfully reproduce the concentration‐ and temperature‐dependent triplet diffusion process, revealing a substantial shift in the ensemble density of states in polar hosts. In gold‐bridged CMAs, this shift does not lead to a significant change in luminescence lifetime, thermal activation energy, reorganization energy, or intersystem crossing rate. These discoveries offer new insight into coupling between the singlet and triplet manifolds in CMA materials, revealing a dominant interaction between states of CT character. The same approach is employed using materials which have been chemically modified to alter the energy of their CT state directly, shifting the emission of sky‐blue chromophores into the practical blue range.     

A series of Er~(3+)-activated SrLaGa_3O_7 single crystal fibers for mid-infrared laser application

A multidisciplinary approach for the production and characterization of a series of high concentration Er~(3+)activated SrLaGa_3 O_7(abbreviated as Er:SLGO) crystal fibers is shown to have a great promise for implementation in mid-infrared laser applications.The current approach includes the design and formation of unique layered tetrahedral network structures with several kinds of rare earth(RE) ions including Er ions distributing statistically between layers,such as Er:SLGO,Er,Nd:SLGO,Er,Yb,Ho:SLGO,Er,Eu:SLGO and Er,Ho:SLGO.Five kinds of Er:SLGO crystal fibers were designed to grow via a micropulling down method.Spectroscopic analyses show that Er,Yb,Ho:SLGO and Nd,Er:SLGO crystal fibers were superiorly endowed with inhomogeneous broadening absorption and strong emission.The unique structural components design enables the generation of improved absorption and emission recombination,and the inhibition of self-termination as well.Generally,the use of structural components design may warrant high-efficiency emissions in RE-doped crystal fibers.     

采煤工作面煤层注水工艺优化与应用

针对目前煤层注水存在的施工钻孔效率低、钻孔深度达不到要求、注水钻孔封孔不严、封孔器回收困难等问题，研究注水工艺的改进优化，对钻机、钻具及封孔器进行重新设计选型，形成了一整套的注水装备。该装备的应用提高了施工效率，为降低工作面粉尘危害、抑制工作面瓦斯涌出、防治煤炭自然发火等危害探索出了更加高效的途径和方法。现场应用表明，煤层注水有效地改善了工作面作业环境，为工作面实现高产高效奠定了基础。     

煤油气共生矿井底板油型气赋存特征及防治

为了提高煤油气共生矿井油型气灾害治理的科学性，以黄陵二矿为例，采用现场测试、钻探取芯、跟踪观测、地质分析等多种方法，研究了采掘工作面煤层底板油型气分布特征、涌出规律和运移机理，并初步探讨了底板油型气体灾害防治措施。结果表明:底板油型气涌出点多位于底板砂岩储层上倾尖灭端和砂岩透镜体附近，呈现不连续区带状分布特征，涌出的油型气主要来自富县组砂岩层，涌出的动力主要为地层流体压力差，底板油型气通过地层中存在大量的断裂和裂缝、微裂缝系统进入采掘空间，采掘扰动是底板油型气异常涌出的工程诱导因素。建议加强油型气综合探查技术、油型气灾害预测预报技术、油型气综合抽采技术和智能化矿井建设等方面的研究。     

Influence of mesoporous phosphotungstic acid on the physicochemical properties and performance of sulfonated poly ether ether ketone in proton exchange membrane fuel cell

This study demonstrates the successful development of hybrid mesoporous siliceous phosphotungstic acid (mPTA-Si) and sulfonated poly ether ether ketone (SPEEK) as a proton exchange membrane with a high performance in hydrogen proton exchange membrane fuel cells (PEMFC). SPEEK acts as a polymeric membrane matrix and mPTA-Si acts as the mechanical reinforcer and proton conducting enhancer. Interestingly, incorporating mPTA-Si did not affect the morphological aspect of SPEEK as dense membrane upon loading the amount of mPTA-Si up to 2.5 wt%. The water uptake reduced to 14% from 21.5% when mPTA-Si content increases from 0.5 to 2.5 wt% respectively. Meanwhile, the proton conductivity increased to 0.01 Scm^?1 with 1.0 wt% mPTA-Si and maximum power density of 180.87 mWcm^?2 which is 200% improvement as compared to pristine SPEEK membrane. The systematic study of hybrid SP-mPTA-Si membrane proved a substantial enhancement in the performance together with further improvement on physicochemical properties of parent SPEEK membrane desirable for the PEMFC application.     

火花放电原子发射光谱类型标准化校正方式的探讨

在国内,火花放电原子发射光谱分析广泛使用类型标准化进行方法校正。在国外,标准和文献中鲜见使用此方法的相关论述。类型标准化主要采用平移校正和转动校正两种方式,哪种方式更加合理也鲜见报道。国外设备类型标准化的默认设置优先采用转动校正方式,相关国内标准对最优校正方式的规定尚不明确,此默认设置的合理性有待探讨。实验选用低合金钢20CrNi2Mo、R407标准样品和不锈钢317L、0Cr18Ni9标准样品,引用国内相关标准,以正确度临界差为评判依据,模拟类型标准化样品和待测样品“十分接近”和“接近”两种情况下平移校正和转动校正的数据正确度。经数据统计分析,平移校正分析结果均满足要求,转动校正结果在“接近”情况下部分元素不满足要求。结合相关国家标准中元素含量范围和精密度数据进行分析,通过计算允许最大偏倚量并制作曲线图方式展开分析,得出如下结论:在满足文中类型标准化控制要点前提下,分析设置更适合于采用平移校正方式。     

Acoustic power measurement of linear compressors

The linear compressor works as an important driver for high frequency regenerative cryocoolers. The acoustic power output of the compressor is a critical parameter in the design and the optimization of a linear compressor. To measure this parameter, several approaches based on different theories have been developed. In this paper, the RC load approach and the back chamber approach have been applied to a linear compressor to measure the acoustic power output. The results measured by the approaches indicate a good consistency with the theoretical calculation and reveal the connections between different approaches.The difference between the acoustic power at the piston surface and the exit of a linear compressor has been analyzed based on the experimental results from the RC load approach and the back chamber approach. The volume flow rate difference which accounts for the acoustic power difference is studied theoretically. Furthermore, based on the RC load approach, the optimum impedance together with the impedance cloudy map for the linear compressor to reach its highest efficiency has been obtained by analyzing the experimental and the theoretical results.     

Biofuel supply chain optimal design considering economic,environmental, and societal aspects towards sustainability

Biofuel supply chain design plays a critical role in facilitating the large‐scale substitution of biofuel for traditional fossil fuels with a cost‐effective and environmentally friendly manner towards sustainability. This paper proposes a multiobjective optimization model for a 4‐layer biofuel supply chain network using mixed integer nonlinear programming while considering the benefits from economic, environmental, and societal aspects. The model can be used either to optimize an existing biofuel supply chain network or to guide the construction of a new biofuel supply chain network. The profit, the greenhouse gas emissions in transportation, and the market share of biofuel were set as targets for optimization. The selection of the participators at each layer, and the amount of the material flow between each pair of selected supplier and customer located at two adjacent layers were modeled as decision variables. The conventional weighted aggregation method was used to unify 3 objectives after normalization. Particle swarm optimization was used to solve this high‐dimension multiobjective problem to obtain a near optimal solution. A numerical case study based on the state of Missouri in the United States was implemented to verify the effectiveness of the proposed model. The results of the case study illustrate that the benefits in terms of transportation emission, profit, and market share can be achieved simultaneously. Using the equal weights configuration in conventional weighted aggregation as an example, a 21% reduction of the transportation emission, a 33% increase of the profit, and a 2% augmentation of the market share were achieved compared to the benchmark scenario.